In the rather polar organic solvents dimethoxyethane, tetrahydrofuran and 3-methyltetrahydrofuran, the behaviour of contact ion pairs, solvent-separated ion pairs and free carbanions of polystyryl sodium has been investigated by kinetic and conductivity measurementsβ’ Both the equilibrium between the
Influence of the structure of the solvent upon the solvation of ion pairs
β Scribed by R. I. Mostkova; Yu. M. Kessler
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1967
- Tongue
- English
- Weight
- 108 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0022-4766
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The solvation structure of the Mn(II), Fe(II), Co(II), Ni(II), and Zn(II) ions has been determined in various nitrogen-donating solvents of npropylamine (PA), trimethylenediamine (TA), ethylenediamine (EN), pyridine (PY), 2-methylpyridine (2MPY), 4-methylpyridine (4MPY), and acetonitrile (AN) by the
Abshact-In order to throw light on ion-solvent interactions, the salvation numbers of electrolytes in different mixed solvents (methanol + water and ethanol + water mixtures) have been determined using ultrasonic interferometer. The anomalies in the salvation number of cations (in aqueous solutions)