Influence of the Structure of the Organic Moiety of Copper(II) Porphyrins on Their Reactivity toward Acids
โ Scribed by O. V. Kosareva; M. E. Klyueva; T. N. Lomova; E. E. Suslova
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 113 KB
- Volume
- 75
- Category
- Article
- ISSN
- 1070-3632
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## Abstract Copper coordination complexes of the neutral tetradentate nitrogenโcontaining ligands tris(3,5โdimethylpyrazolโ1โylmethyl)amine (L0N4) and tris(3,5โdiisopropylpyrazolโ1โylmethyl)amine (L1N4), namely the copper(II) chlorido complexes [Cu^II^(L0N4)Cl~2~] (1) and [Cu^II^(L1N4)Cl~2~] (2), t
Reported here are the novel free porphyrins corallistin B, C, D, and E, isolated as methyl esters 2a, 3a, 4a, and 5a, respectively, from the sponge Cordistes sp. (Lithistida) collected at the basis of the south New Caledonian coral reef. A protocol is also established for formylation of their Ni" co