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Influence of the stereo-defect distribution on the crystallization behavior of Ziegler-Natta isotactic polypropylene

✍ Scribed by Jian Kang, Ya Cao, Huilin Li, Jingping Li, Shaohua Chen…


Book ID
120741032
Publisher
Springer
Year
2012
Tongue
English
Weight
946 KB
Volume
19
Category
Article
ISSN
1022-9760

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The formation of isotactic polypropylene
✍ P. Cossee 📂 Article 📅 1960 🏛 Elsevier Science 🌐 French ⚖ 209 KB

IN a previous publication 1 on the meohanism of the ethylene polymerization with heterogeneous 'Ziegler-Natta catalyst systems it was pointed out how an ethylene molecule is interposed between a Ti-ion and an alkyl group. The active center of the catalyst in the growth reaction was considered to be

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A small-and wide-angle X-ray scattering study was performed on two metallocene catalyzed isotactic polypropylene (miPP) resins. The results were compared with two similar molecular weight Ziegler-Natta catalyzed isotactic polypropylene (zniPP) materials. Wide-angle X-ray diffraction (WAXD) results s