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Influence of the stationary gas chromatographic phase on the elution order of 2,4,5-substituted polychlorinated biphenyls

✍ Scribed by Walter Vetter; Bernd Luckas; Manfred Mohnke

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 566 KB
Volume: 8
Category: Article
ISSN: 1040-7685
DOI: 10.1002/(sici)1520-667x(1996)8:3<183::aid-mcs3>3.0.co;2-y

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✦ Synopsis

The elution order of the 2,4,5-substituted PCB congeners was determined on four capillary columns (CP-Select for PCBs, CP-Sil 8/20% C-18, CP-Sil 19, and CP-Sil 88) with a wide range of polarity. Normalizing of the retention times of these PCB congeners allowed us to compare the influence of the structure on the retention times on different columns. Several trends were derived which were attributed to the different polarities of the phases. The trends were discussed by comparing the influence of the structure on selected PCB separation problems.

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