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Influence of the Solvent on the Stereoselectivity of 1,3-Dipolar Cycloaddition of Nitrile Oxides on Several 4-Substituted 2-Cyclopentenones.

โœ Scribed by Giorgio Adembri; M. Laura Paoli; Alessandro Sega


Publisher
John Wiley and Sons
Year
2003
Weight
139 KB
Volume
34
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Influence of a 2-Fl
โœ M. IHARA; Y. TANAKA; N. TAKAHASHI; Y. TOKUNAGA; K. FUKUMOTO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 2 views

Influence of a 2-Fluoro Substituent on Diastereoselectivity in the 1,3-Dipolar Cycloadditions of Nitrones. -2-Fluoro nitrones, e.g. (IIIa)-(IIIc), show reverse diastereoselectivity in the title reaction compared with 2-hydro nitrones such as (IIId)-(IIIf). It is noteworthy that no appropriate catal