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Influence of the size of the counter-ion on the conformational stability of the alkali metal complexes of 2,2'-dithienyl ketyl

โœ Scribed by G.F. Pedulli; A. Alberti


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
312 KB
Volume
26
Category
Article
ISSN
0009-2614

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Solvent influence on the conformational
โœ Jerzy Kalenik; Zbigniew Paweล‚ka ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 168 KB

The relative energies and dipolar properties of two conformers of 2,2V-bipyridine (1) were calculated using AM1 and ab initio methods. Dipole moments of 1 and pyridine in many organic solvents were determined. On this basis, the Gibbs energy DG (s) for the conformational s-transWs-cis equilibrium of