Influence of the nature of the organometallic component of the complex catalyst on the kinetics of the stereospecific polymerization of propylene
β Scribed by A. P. Firsov; N. M. Chirkov
- Book ID
- 112419447
- Publisher
- Springer
- Year
- 1964
- Tongue
- English
- Weight
- 378 KB
- Volume
- 13
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
## Abstract The kinetics of propylene polymerization catalyzed by a commercial sample of highly activated titanium trichloride and diethylaluminum chloride have been investigated. Polymerizations were carried out at various temperatures, pressures, and catalyst concentrations, and reaction rates we
There is further consideration of the model of the active site of polymerization on heterogeneous Ziegler-Natta catalysts. It is located on basal planes of lattice crystals of type a-TiCl3 or VCI3 and has two vacancies at the transition metal atom. One of these vacancies is blocked by the helical po