The nature of the metal๎ธmetal interactio
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C.David Garner; Ian H. Hillier; Martyn F. Guest; Jennifer C. Green; Anthony W. C
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Article
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1976
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Elsevier Science
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English
โ 395 KB
The results of an ab initio molec&r orbital caliculatio~ for Cr2(0$ZH)~,2H20 are presented. They indicate that the eight chromium d electrons, corresponding to a d4 configuration of each metal atom are accommodated in the metal-metal u, 6,6\* and o\* orbita!s to give no net bonding over the Cr-Cr se