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Influence of the nature of the ligands on the metal-metal interaction in Cu(II) alkanoates

โœ Scribed by Yu. V. Yablokov; V. V. Gavrilov; L. N. Milkova; A. V. Ablov


Publisher
SP MAIK Nauka/Interperiodica
Year
1971
Tongue
English
Weight
535 KB
Volume
12
Category
Article
ISSN
0022-4766

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The results of an ab initio molec&r orbital caliculatio~ for Cr2(0$ZH)~,2H20 are presented. They indicate that the eight chromium d electrons, corresponding to a d4 configuration of each metal atom are accommodated in the metal-metal u, 6,6\* and o\* orbita!s to give no net bonding over the Cr-Cr se