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Influence of the monomer nature on the activity of the supported titanium catalyst of polymerization of α-olefins

✍ Scribed by N.M. Gul'tseva; T.M. Ushakova; A.M. Aladyshev; L.N. Raspopov; I.N. Meshkova

Book ID
116049974
Publisher
Elsevier Science
Year
1991
Weight
385 KB
Volume
33
Category
Article
ISSN
0032-3950

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Stereoelective polymerization of racemic
Stereoelective polymerization of racemic α-olefins: Influence of conversion and of nature of catalyst components
✍ Carlini, Carlo ;Bano, Hussan ;Chiellini, Emo 📂 Article 📅 1972 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 718 KB

## Abstract The dependence of stereoelectivity on conversion has been investigated by polymerizing racemic 4‐methyl‐1‐hexene (I) and 3,7‐dimethyl‐1‐octene (II) in the presence of catalysts prepared from TiCl~4~ and bis[(S)‐2‐methylbutyl]‐zinc(III) or tris [(S)‐2‐methylbutyl]aluminum (IV). The influ