Influence of the host on vibronic relaxation: a study of free-base porphin in a series of n-alkanes by photochemical hole-burning
✍ Scribed by A.I.M. Dicker; S. Völker
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 427 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Photochemlcal holc-burnmg IS uxd to detemunc rhc rclzmon woes oi vlbromc bands of the S, -So transmon of free-base porphm III ddlercnt subwwtIona1 sites oTrr-lle~nc,rl-hcpt~c,fr-oct3nr and ,Idccmc at 1 6 K.. Tbr wbromc rc-Iaalion depends strongly on WC and host. A correlation bctaeen the rr-alka~e than length and the wbronrc rclxG!on time is obscncd.
📜 SIMILAR VOLUMES
Tr.msien: and photochemical hole-burning is used to determine the homqeneous linewidths of the S, + So and Su t So . transitions of a magwsium porphin-pyridine comptex in four sites of n-octane (T= 1.1-4.2 I;). Thermally induced dephas-' ins of S, .-So is consistent 1% ith "exchange" to low-frequenc