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Influence of the host on vibronic relaxation: a study of free-base porphin in a series of n-alkanes by photochemical hole-burning

✍ Scribed by A.I.M. Dicker; S. Völker


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
427 KB
Volume
87
Category
Article
ISSN
0009-2614

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✦ Synopsis


Photochemlcal holc-burnmg IS uxd to detemunc rhc rclzmon woes oi vlbromc bands of the S, -So transmon of free-base porphm III ddlercnt subwwtIona1 sites oTrr-lle~nc,rl-hcpt~c,fr-oct3nr and ,Idccmc at 1 6 K.. Tbr wbromc rc-Iaalion depends strongly on WC and host. A correlation bctaeen the rr-alka~e than length and the wbronrc rclxG!on time is obscncd.


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Homogeneous linewidth and optical dephas
✍ A.I.M. Dicker; L.W. Johnson; S. Völker; J.H. van der Waals 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 654 KB

Tr.msien: and photochemical hole-burning is used to determine the homqeneous linewidths of the S, + So and Su t So . transitions of a magwsium porphin-pyridine comptex in four sites of n-octane (T= 1.1-4.2 I;). Thermally induced dephas-' ins of S, .-So is consistent 1% ith "exchange" to low-frequenc