Influence of the guest molecules on the protonic conduction of anhydrous intercalation compounds of α-Zirconium hydrogen phosphate with diamines

Intercalation compounds of α-zirconium h

Intercalation compounds of α-zirconium hydrogen phosphate with Rh3+ ions and Rh3+-diamine complexes. Part II. Their behaviour towards CO, CO2 and H2 and their use in the CO catalytic oxidation

✍ P. Giannoccaro; A.La Ginestra; M.A. Massucci; C. Ferragina; G. Mattogno 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 924 KB

The reactivity of Rh3+ ions and Rh3+ -diamine CI-ZI(HPOJ~ . H,O complexes intercalated in a-zirconium hydrogen phosphate towards small molecules (CO, 0,, H2) was studied. The compounds only containing Rh3+ ions, of composition ZrH,Rh,(PO,)z .4H,O (X = 2 -3y; 0 < y I 0.66) react with CO at atmospheri