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Influence of the geometry around the manganese ion on the peroxidase and catalase activities of Mn(III)–Schiff base complexes

✍ Scribed by M. Ángeles Vázquez-Fernández; Manuel R. Bermejo; M. Isabel Fernández-García; Gustavo González-Riopedre; M. Jesús Rodríguez-Doutón; Marcelino Maneiro

Book ID: 113718542
Publisher: Elsevier Science
Year: 2011
Tongue: English
Weight: 855 KB
Volume: 105
Category: Article
ISSN: 0162-0134
DOI: 10.1016/j.jinorgbio.2011.09.002

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## Abstract Rate constants for the hydrolysis (__k__~h~) of six different amines in __trans‐__[Co((BA)~2~en)(amine)~2~]ClO~4~ complexes (amine = aniline 1a, para‐toluidine 1b, benzylamine 1c (primary amines), pyrrolidine 2a, piperidine 2b, morpholine 2c (secondary amines), and (BA)~2~en = Bisbenzoy