Influence of the Chemical Structure of MADIX Agents on the RAFT Polymerization of Styrene
β Scribed by Adamy, Monique; van Herk, Alex M.; Destarac, Mathias; Monteiro, Michael J.
- Book ID
- 126325094
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 205 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0024-9297
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## Abstract Eight xanthates were synthesized to induce living free radical polymerization of vinyl acetate. Four compounds, methyl (4βmethoxyphenoxy)carbonothioylsulfanyl acetate, methyl (methoxycarbonothioyl)sulfanyl acetate, methyl (ethoxycarbonothioyl)sulfanyl acetate and methyl (isopropoxycarbo
## Abstract Control of the freeβradical polymerization of styrene was achieved using a series of eight xanthates of the general structure Rο£ΏS(Cο£ΎS)OEt as reversible addition fragmentation chainβtransfer agents. The influence of the nature of the R leaving group was explored. It was found that the tr