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Influence of the bridging azine ligand on the rate of ligand substitution in a series of dinuclear platinum(II) complexes

✍ Scribed by D. Reddy; D. Jaganyi

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
433 KB
Volume
43
Category
Article
ISSN
0538-8066

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✦ Synopsis

Perchlorate salts are known to be explosive oxidizers, and their use warrants extra caution. Sodium perchlorate in particular is a known irritant and targets human tissue and organs, viz. the thyroid and blood.

† Thiourea and its substituted derivatives are suspected carcinogens and the necessary safety precautions must be adhered to when handling these reagents.

Found: C, 5.84; H, 2.06; N, 10.44. IR ‑ (KBr) cm

πŸ“œ SIMILAR VOLUMES

Role of bridging diamine linkers on the
Role of bridging diamine linkers on the rate of ligand substitution in a series of dinuclear PtII complexes
✍ D. Jaganyi; V. M. Munisamy; D. Reddy πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 215 KB πŸ‘ 1 views

## Abstract A series of dinuclear platinum^II^ complexes of the type [{__trans__‐Pt(H~2~O)(NH~3~)~2~}~2~‐NH~2~(CH~2~)~n~H~2~N]^4+^ (where __n__ = 2, 3, 4, and 6) were synthesized to investigate the influence of the bridging diamine linker on the reactivity of the platinum centers. The p__K__~a~ val