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Influence of the 6-trimethylsilyl group on the fragmentation of the trimethylsilyl derivatives of some 6-hydroxy- and 3,6-dihydroxy-steroids and related compounds

✍ Scribed by David J. Harvey; Paul Vouros


Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
771 KB
Volume
6
Category
Article
ISSN
1076-5174

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On the Behavior of 5,8-Bis(trimethylsily
✍ Michael A. Hofmann; Anja Nachbauer; Uwe BergstrÀßer; Manfred Regitz πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 361 KB

Phosphaalkynes 2 and electron-deficient alkynes 11 readily configuration of the phophatricyclodecadienes 12. In solution the tricyclodecadienes 13 are prone to facile cycloreversion react in a [4 + 2] cycloaddition process with 5,8bis(trimethylsilyl)cycloocta-1,3,6-triene (8) in its bicyclic form yi