𝔖 Bobbio Scriptorium
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Influence of synthesis on the structure of electrochemically prepared electrically conducting polymers

✍ Scribed by Mitchell, G. R. ;Davis, F. J. ;Kiani, M. S.

Book ID
104528019
Publisher
Wiley (John Wiley & Sons)
Year
1990
Tongue
English
Weight
702 KB
Volume
23
Category
Article
ISSN
0007-1641

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✦ Synopsis

Abstract

The inherent possibility of structural anisotropy in polypyrrole and other heterocyclic systems is introduced. By selecting the appropriate electrochemical variables including monomer and dopant type this intrinsic molecular anisotropy may be used to prepare films with well defined global anisotropy, in which the planes of the pyrrole rings prefer to lie parallel to the electrode surface. The conditions for obtaining such materials are discussed and some of the effects of these novel anisotropic structures on the resultant properties are highlighted. Attention is directed at charge transport and optical properties.

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