Influence of substituents on rate constants for recombination of secondary and primary peroxy radicals
β Scribed by Khursan, S. L. ;Martemyanov, V. S.
- Book ID
- 112688704
- Publisher
- Springer
- Year
- 1989
- Tongue
- English
- Weight
- 225 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0133-1736
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π SIMILAR VOLUMES
## Abstract A flash photolysis setup coupled to UV absorption spectrometry detection was used to measure the UV absorption spectra of the (CH~3~)~2~(CH~2~O~2~.)CC(O)C(CH~3~)~3~ and (CH~3~)~2~(CH~2~O~2~.)CC(O)CH~3~ radicals between 207 and 290 nm. The selfβreaction rate constants of these radicals w
Calculations were carried out on several data sets to study the mechanism of hydrogen abstraction from phenols by peroxy radicals: (1) Rate constants, k values, were collected for the reactions of cumyl-, l-phenylethyland tert-butyl-peroxy radicals with ortho-para-substituted phenol inhibitors. Th