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Influence of substituents on C(6) of 4,4-dimethyl-2-cyclohexanone on photoaddition vs. photocycloaddition to 2-methylpropane

✍ Scribed by Guliano Cruciani; Christoph Semisch; Paul Margaretha

Book ID
103991633
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
383 KB
Volume
44
Category
Article
ISSN
1010-6030

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## Abstract n‐π^\*^ Excitation of 6‐fluoro‐4,4‐dimethyl‐2‐cyclohexenone in the presence of 2,3‐dimethyl‐2‐butene leads selectively to the formation of the corresponding oxetane. The factors which influence the oxetane __vs.__ cyclobutane formation ratio in photoadditions of cyclic enones to olefins