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Influence of steric effects on regio- and stereospecificity of adding thiolates to tert-butylacetylene

โœ Scribed by V. I. Laba; A. V. Sviridova; A. A. Kron; V. N. Dudnikova; E. N. Prilezhaeva

Book ID
112438637
Publisher
Springer
Year
1974
Tongue
English
Weight
63 KB
Volume
23
Category
Article
ISSN
1573-9171

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An examination of the steric effects of
An examination of the steric effects of 5-tert-butylproline on the conformation of polyproline and the cooperative nature of type II to type I helical interconversion
โœ Eric Beausoleil; William D. Lubell ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 114 KB ๐Ÿ‘ 2 views

The influence of steric effects on the helical geometry and the interconversion of type II to type I polyproline in water was examined by the synthesis and analysis of proline dimers and hexamers containing up to three (2S,5R)-5-tert-butylproline residues. In the dimers, the bulky 5-tert-butyl subst