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Influence of solvents on the radical decomposition of ketohydroperoxide

✍ Scribed by G. E. Zaikov; Z. K. Maizus; N. M. Émanuél'


Book ID
112435931
Publisher
Springer
Year
1968
Tongue
English
Weight
421 KB
Volume
17
Category
Article
ISSN
1573-9171

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The synthesis and rates of decomposition of bis(l,l-dimethyl-2-oxopropyl) diazene (2~) are described. A series of substituted azoalkanes is compared to four other systems measuring radical substituent effects. These correlations and a solvent polarity study indicate the lack of polar contributions