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Influence of Ring-Size of Cycloalkenes on the Activation Volume in the High-Pressure Copolymerization of Maleic Anhydride

✍ Scribed by Dr. Gérard Jenner; Dr. Mohamed Kellou; Dr. Mihalis Papadopoulos


Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
219 KB
Volume
21
Category
Article
ISSN
0044-8249

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Cloud point data to 230°C and 2200 bar are presented for poly(acrylate)ethylene mixtures. When the length of the alkyl tail is increased, the cloud point curve is shifted towards lower pressure, but this trend switches when going from poly(ethyl hexyl) to poly(octadecyl) acrylate. It is apparent tha