Influence of processing on the Li:Mn ratio in spinel phases of the system Li1 + xMn2 − xO4 − δ
✍ Scribed by P. Endres; B. Fuchs; S. Kemmler-Sack; K. Brandt; G. Faust-Becker; H.-W. Praas
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 914 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0167-2738
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Electrochemical and x-ray diffraction measurements have been performed on two lithium deficient lithium manganese oxide phases, namely Li,,,~Mn,O, and Lip,csMntO,. These materials were prepared by a chemical oxidative treatment of the parent LiMn,O, spmel phase in acidic conditions. The results are
packed structures was further extended by Goodenough's group to 3-D materials with the spinel structure (3). It was Lithium manganospinels belonging to the LiMn 2 O 4 -Li 2 Mn 4 O 9 -Li 4 Mn 5 O 12 system were prepared by solid-state reac-shown that lithium could be intercalated into the spinels tio