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Influence of powder morphology on thermoelectric anisotropy of spark-plasma-sintered Bi–Te-based thermoelectric materials

✍ Scribed by Dong Hwan Kim; Cham Kim; Seong Hyeon Heo; Hoyoung Kim


Book ID
103999172
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
876 KB
Volume
59
Category
Article
ISSN
1359-6454

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✦ Synopsis


The influence of the starting powders' morphology on the thermoelectric anisotropy of Bi-Te-based thermoelectric materials that are fabricated by spark plasma sintering has been investigated. Starting powders with three types of morphologies are prepared through a chemical reaction method (nano-sized particles with a spherical shape), a conventional pulverization method (flake-like shape) and a gas atomizing method (spherical shape). The thermoelectric anisotropy of each sintered body is determined by measuring the electrical resistivity and thermal conductivity in both the parallel and perpendicular directions to the spark plasma sintering pressing direction. The p-type Bi 0.5 Sb 1.5 Te 3.0 -sintered body that is composed of the spherically shaped powder has isotropic thermoelectric properties, while the same material composed of the flake-like powder shows anisotropic behavior. The n-type Bi 2 Te 3 sintered body has a relatively small anisotropy when it is composed from the spherically shaped powder.


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