Time-resolved resonance Raman spectra of free-base tetraarylporphyrins were obtained to investigate the peripheral substituent effect on the structural changes in the excited states. The aryl mode of H2-tetratoluylporphyrin in the excited triplet state was more strongly enhanced relative to that of
Influence of peripheral substituents on the resonance Raman spectra of ferroporphyrin-2-methylimidazole complexes
β Scribed by Alain Desbois; Yann Henry; Marc Lutz
- Book ID
- 113264600
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 850 KB
- Volume
- 785
- Category
- Article
- ISSN
- 0167-4838
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π SIMILAR VOLUMES
The resonance Raman (RR) spectra of the "Oz adducts of the imidazole complexes of a highly protected cobalt "jellyfish" porphyrin are reported. The complex spectral patterns observed in the RR spectra are interpreted as a result of vibrational coupling of the v('~O-~~O) with internal modes of the co
## Abstract Resonance Raman spectra are reported for a series of systematically deuterated analogues of myoglobin in its deoxy state as well as for its CO and O~2~ adducts. Specifically, the myoglobin samples studied are those that have been reconstituted with deuterated protoheme analogues. These