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Influence of peripheral ligands on the metal-metal interaction in dinuclear metal complexes with N-heterocyclic bridging ligands

✍ Scribed by Gaetano Giuffrida; Sebastiano Campagna


Book ID
113138671
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
1018 KB
Volume
135-136
Category
Article
ISSN
0010-8545

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## Abstract To explore the metal–metal interaction and spectroscopic properties, the ground‐ and excited‐state structures of [M~2~(dpm)~2~]^2+^ [M = Ag (2), Cu (3), dpm = bis(diphosphanyl)methane] and their solvated species [M~2~(dpm)~2~]^2+^·(MeCN)~2~ were optimized by the MP2 and CIS methods, res