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Influence of particle size on the phase behavior associated with the thermal spin transition of the Prussian blue analogue K0.4Co1.3[Fe(CN)6]·4.4H2O

✍ Scribed by Andrus, Matthew J.; Calm, Yitzi M.; Knowles, Elisabeth S.; Dumont, Matthieu F.; Abboud, Khalil A.; Meisel, Mark W.; Talham, Daniel R.


Book ID
121646371
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
959 KB
Volume
64
Category
Article
ISSN
0277-5387

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Nanoparticles of [Fe(NH2-trz)3]Br2⋅3 H2O
✍ Thibaut Forestier; Abdellah Kaiba; Stanislav Pechev; Dominique Denux; Philippe G 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 854 KB

## Abstract By changing the surfactant/water ratio, nanoparticles of the iron(II) spin crossover material, [Fe(NH~2~‐trz)~3~]Br~2~⋅3 H~2~O (with NH~2~‐trz=4‐amino‐1,2,4‐triazole), have been synthesised from 1 μm down to 30 nm (see figure). Magnetic and reflectivity experiments indicate that the cri