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Influence of nitroxyl radical center on keto-enol equilibrium of β-keto-esters of 3-imidazoline derivatives

✍ Scribed by I. A. Grigor'ev; G. I. Shchukin; V. I. Mamatyuk; L. B. Volodarskii


Book ID
112442348
Publisher
Springer
Year
1985
Tongue
English
Weight
460 KB
Volume
34
Category
Article
ISSN
1573-9171

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The enol content and equilibrium free energies for the keto-enol tautomerism have been determined for a series of 1,3-diketones, at 40 OC, in deuterochloroform and dimethylsulfoxide-d (DMSO), by lH n.m.r.. Compounds containing methyl, phenyl, t-butyl, E-thienyl, trifluorome t hyl and ethoxy groups h