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Influence of N6-methylation of residue A(5) on the conformational behaviour of d(C-C-G-A-A-T-T-C-G-G) in solution studied by 1H-NMR spectroscopy : 2. The hairpin form

✍ Scribed by Lambertus J. RINKEL; Gijs A. van der MAREL; Jacques H. van BOOM; Cornelis ALTONA


Book ID
115124968
Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
864 KB
Volume
163
Category
Article
ISSN
1432-1327

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The NOESY spectrum and vicinal coupling constants of t(4)-acetoxy-3,3-dimethyl-r(2),c(6)-diphenyl-Nacetylpiperidine suggest that the compound adopts a chair conformation with axial phenyl groups. The vicinal coupling constants of t(4)-acetoxy-r(2),c(6)-diphenyl-N-acetylpiperidine could be accounted