The use of organic solvents in the oxidation of I-dodecanethiol, catalyzed by cobalt( II) phthalocyanine-tetrasodiumsulfonate (CoPc(NaSO,),) /2,4-ionene, drastically influences the reaction mechanism. Without an organic solvent the reaction proceeds at the thiol-water phase boundary, where the ionen
✦ LIBER ✦
Influence of Molecular Weight of Ionenes on the Cobalt Phthalocyanine-Catalyzed Oxidation of 1-Dodecanethiol
✍ Scribed by Schipper, Eugene T. W. M.; Roelofs, Alexander H. C.; Piet, Pieter; German, Anton L.
- Book ID
- 126430581
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 580 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0743-7463
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## Abstract Polyphenylene oxide (PPO) was prepared via oxidative coupling polymerization of 2,6‐dimethylphenol (DMP) catalyzed by copper salt. The ligand was a novel series of random copolymers (PSVP) of styrene and 4‐vinylpyridine prepared by reversible addition‐fragmentation chain transfer (RAFT)