Influence of mixing and solid concentration on sodium bicarbonate secondary nucleation rate in stirred tank
✍ Scribed by C. Wylock; V. Gutierrez; F. Debaste; T. Cartage; M.-P. Delplancke-Ogletree; B. Haut
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 418 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0232-1300
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✦ Synopsis
Abstract
This work aims to investigate the influence of the solid concentration in suspension on the contact secondary nucleation rate of sodium bicarbonate crystallization in a stirred tank crystallizer and to show the necessity of a local description of the mixing for a nucleation rate influence study. Experiments and computational fluid dynamics (CFD) simulations are realized. Crystallization kinetic parameters are extracted from experimental data using a mass distribution fitting approach. CFD and the experimental results allow identifying that a mixing property correlated with the measurements of the secondary nucleation rate in the stirred tank crystallizer appears to be the turbulent dissipation rate on the edge of the impeller. Its influence and the influence of the solid concentration in the suspension on the secondary nucleation rate are estimated by the evaluation of their exponents in a kinetic law. The obtained exponent values are then discussed qualitatively. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)