## Abstract For Abstract see ChemInform Abstract in Full Text.
Influence of methoxy-and methyl-aromatic substituents on stereochemistry of the products in the acid-catalyzed cyclization of 2-(2-arylethyl)-1,3,3-trimethylcyclohexanols: stereocontrolled total synthesis of (±)-nimbidiol and (±)-nimbiol
✍ Scribed by Bimal K. Banik; Sukumar Ghosh; Usha Ranjan Ghatak
- Book ID
- 104203817
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 723 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4020
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✦ Synopsis
The distributions of the trans-and the cis-podocarpatrienes
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## Abstract Acid treatment of 9__exo__‐methyl‐__anti__^10,11^‐tricyclo[4.2.1.1^2,5^]deca‐3,7‐diene‐9__endo__, 10__endo__‐diol (**8**) leads to the two isomeric pentacyclic ethers **7** and **9** by intramolecular nucleophilic substitution of a protonated OH‐group with participation of a C,C‐double