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Influence of methacrylic acid dimerization on the configurational and compositional triad sequences in methacrylic acid-methyl methacrylate copolymers

✍ Scribed by G.S. Georgiev; I.G. Dakova

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
278 KB
Volume
31
Category
Article
ISSN
0014-3057

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✦ Synopsis

The influence of methacrylic acid (A) dimerization in toluene on its copolymerization with methyl meth.acrylate (B) was studied. It was established that as a result of this influence the dependence of the conAgurationa1 triad mole fraction on the monomer feed is non-linear, r, = 1.05 k 0.03, rs = 0.05 f 0.02 and the experimental values of the alternating ABA and BAB compositional triads are rather smaller than those calculated by the terminal model which does not take account of the dimer participatiou in the chain propagation.

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