## Abstract A spherical TiCl~4~/MgCl~2~‐based catalyst was used in the synthesis of __in situ__ isotactic polypropylene/ethylene–propylene random copolymer blends by propylene bulk polymerization and subsequent gas‐phase copolymerization of ethylene with propylene. Different copolymerization condit
Influence of mechanical properties in carbon black (CB) filled isotactic polypropylene (iPP) and propylene-ethylene block copolymer
✍ Scribed by Hsien-Tang Chiu; Wei-Ming Chiu
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 806 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0021-8995
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✦ Synopsis
The mechanical properties of isotactic polypropylene (iPP) and propylene-ethylene block copolymer (Co-PP) with carbon black (CB) were added as a filler. By mixing appropriate amounts of the two components through melt-blending in a twin-screw extruder, the blended pellets were prepared to a series of test specimens by injection molding. A scanning electron microscopic study was performed of the morphologies of the impact fractured surfaces. The blending of CB in Co-PP not only improves the impact strength, but also improves the flexural modulus and tensile strength; however, the heat distortion temperature (HDT) of the Co-PP/CB blends decreased with greater filler content. Furthermore, the filler of CB improves the tensile yield strength only at low filler content in iPP/CB blends, and the heat distortion temperature (HDT) and flexural modulus of the iPP/CB blends increased with greater filler content. The impact behavior is not good for the iPP/CB blends. Overall, Co-PP/CB has better interaction of molecules than iPP/CB.
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