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Influence of ionic liquids on the phase transfer-catalysed enantioselective Michael reaction

✍ Scribed by Ravindra T. Dere; Ravindra R. Pal; Prashant S. Patil; Manikrao M. Salunkhe

Book ID
104253872
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
79 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

The enantioselective Michael addition of dimethyl malonate to 1,3-diphenylprop-2-en-1-one promoted by a quaternary derived ammonium salt from quinine as a phase transfer catalyst in different ionic liquids, 1-butyl-3-methyl imidazolium hexafluorophosphate, [bmim]PF 6 , 1-butyl-3-methyl pyridinium tetrafluoroborate, [bpy]BF 4 , 1-butyl-3-methyl imidazolium tetrafluoroborate [bmim]BF 4 as well as in conventional organic solvents was studied.

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