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Influence of intersite modes on the exchange interaction in electron transfer at large distances

✍ Scribed by J. N. Onuchic; A. A. S. Gama

Publisher
Springer
Year
1986
Tongue
English
Weight
595 KB
Volume
69
Category
Article
ISSN
1432-2234

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In the context of the finite sink approximation, a parametrization of diffusion-limited electron transfer quenching of 9,10-dicyanoanthracene fluorescence by "rr' and 'n' donors is reported. The effective transfer distance R increases with exergonicity for "rr' donors (as shown by previous authors)