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Influence of Equatorial and Axial Carboxylato Ligands on the Kinetic Inertness of Platinum(IV) Complexes in the Presence of Ascorbate and Cysteine and within DLD-1 Cancer Cells

โœ Scribed by Chen, Catherine K. J.; Zhang, Jenny Z.; Aitken, Jade B.; Hambley, Trevor W.

Book ID
126800000
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
538 KB
Volume
56
Category
Article
ISSN
0022-2623

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The Influence of the Axial Ligands of a
The Influence of the Axial Ligands of a Series of Platinum(IV) Anti-Cancer Complexes on Their Reduction to Platinum(II) and Reaction With DNA
โœ Ellis, LT; Er, HM; Hambley, TW ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Commonwealth Scientific and Industrial Research Or ๐ŸŒ English โš– 612 KB

The electrochemical reduction and DNA binding have been studied for a series of platinum(IV) complexes with Cl-, OH-, and carboxylate anions as the axial ligands ; [Pt(en)Cl4], [Pt(en)Cl2(OH)2], and [Pt(en)Cl2(OC(O)R)2], R = CH3, CH2CH3, CH2CH2CH3. Cathodic reduction potentials vary by more than 650