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Influence of Environment on the Electronic Structure of Cob(III)alamins: Time-Resolved Absorption Studies of the S 1 State Spectrum and Dynamics

✍ Scribed by Harris, D. Ahmasi; Stickrath, Andrew B.; Carroll, Elizabeth C.; Sension, Roseanne J.

Book ID: 125888089
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 293 KB
Volume: 129
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja066197y

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## Abstract We have synthesized ruthenium(II)– and osmium(II)–polypyridyl complexes ([M(bpy)~2~**L**]^2+^, in which M=Os^II^ or Ru^II^, bpy=2,2′‐bipyridyl, and **L**=4‐(2,2′‐bipyridinyl‐4‐yl)benzene‐1,2‐diol) and studied the interfacial electron‐transfer process on a TiO~2~ nanoparticle surface usi