Influence of drawing and molecular weight on structural-mechanical properties of acrylic fibers
β Scribed by A. I. Stoyanov; V. P. Kpestev
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- English
- Weight
- 265 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
Abstract
The influence of drawing and molecular weight in a narrow range on the several structuralβmechanical properties of acrylic fibers have been investigated. Drawing of fibers (Ξ» = 3__x__β6,5__x__) leads to a considerable increase of tenacity. These data were explained with the orientation and perfection of structure. It was found that the molecular weight in closer range influences the density, perfection of structure, and the stability of fibers to repetitive deformation. The results show that the diversions of the average molecular weight, in the manufacture of commercial acrylic fibers, must be negligible.
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The acrylic fibers containing 10.8 wt % of acrylic acid as a comonomer were treated with 5% aqueous solution of sulphates of alkali metals (sodium and potassium) and transition metals (cobalt and nickel) at 90ΠC for 5 min. The effect of this treatment on the chemical structure, thermal behavior and
The effect of polymer concentration on the structural mechanical properties of acrylic fibers was investigated. The dope concentration, independent of molecular weight, influences the tenacity, loop tenacity, density, perfection of the structure, and the stability of fibers to repetitive deformation