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Influence of Diffusion on the Kinetics of Donor−Acceptor Electron Transfer Monitored by the Quenching of Donor Fluorescence

✍ Scribed by Gladkikh, V. S.; Burshtein, A. I.; Tavernier, H. L.; Fayer, M. D.

Book ID
126334422
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
104 KB
Volume
106
Category
Article
ISSN
1089-5639

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Two cyclophk~s are studied which contain the same electron donor-acceptor pan but in a different orientation. The transition probability of charge-tiansfer fluorescence and of charge-transfer absorption IS found tc depend strongly on the rektne donor-acceptor oricntatlon. Increese of solvent polarit