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Influence of Copper−Sulfur Covalency and Copper−Copper Bonding on Valence Delocalization and Electron Transfer in the Cu A Site of Cytochrome c Oxidase ‖

✍ Scribed by Williams, Kendra Rose; Gamelin, Daniel R.; LaCroix, Louis B.; Houser, Robert P.; Tolman, William B.; Mulder, Ton C.; de Vries, Simon; Hedman, Britt; Hodgson, Keith O.; Solomon, Edward I.


Book ID
126482244
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
101 KB
Volume
119
Category
Article
ISSN
0002-7863

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An investigation of the valence states of thallium and copper in some high-To superconducting layered thallium cuprates has been undertaken by XAS at T1 Lm-and copper K-edges. At the thallium Lm-edge, a general shift of the edge transitions towards low energies has been observed on the superconducto