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Influence of components of the PdCl2(PPh3)2-PPh3-p-toluenesulfonic acid catalytic system on the rate of cyclohexene hydrocarbalkoxylation withm-cresol

✍ Scribed by V. A. Aver’yanov; N. M. Nosova; E. V. Astashina; N. T. Sevost’yanova


Book ID
110196627
Publisher
Springer
Year
2007
Tongue
English
Weight
262 KB
Volume
47
Category
Article
ISSN
0965-5441

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Hydroesterification of cyclohexene using
✍ Andrea Vavasori; Luigi Toniolo; Gianni Cavinato 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 194 KB

The hydroesterification of cyclohexene is catalyzed by a preformed Pd(PPh 3 ) 2 (TsO) 2 complex I in methanol as solvent. The effect of PPh 3 , TsOH, and water on the TOF has been evaluated. The system I/PPh 3 /TsOH = 1/6/8, in the presence of 800 ppm of H 2 O, at 373 K and under 2.0 MPa of CO leads