Influence of certain halogen compounds on the oxidation of U(IV) in a sulfuric medium
β Scribed by G. M. Nesmeyanova; A. I. Vikulov
- Book ID
- 112483074
- Publisher
- Springer US
- Year
- 1964
- Tongue
- English
- Weight
- 350 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1573-8205
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π SIMILAR VOLUMES
T h e kinetics of the reaction (1) U (IV) + H202 UO;' + 2H+ have heen investigated in HzSO4 medium under different conditions. 'The observed bimolecular rate constant kobs, has been found to depend on [H+]-'l.ss and to increase with the initial concentration ratio of the reactants Ro = [H20~]o/[U (I
## Abstract Kinetics of the oxidation of Dβfructose by cerium(IV) has been investigated both in the absence and presence of surfactants (cetyltrimethylammonium bromide, CTAB, and sodium dodecyl sulfate, SDS) in sulfuric acid medium. The reaction exhibits firstβorder kinetics each in [cerium(IV)] an