Influence of Ca(OH)2 and CaSO4 · 2H2O on hydration reaction of amorphous calcium aluminate
✍ Scribed by K. Nakagawa; I. Terashima; K. Asaga; M. Daimon
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 672 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0008-8846
No coin nor oath required. For personal study only.
✦ Synopsis
The influences of Ca(OH)z and CaSO4 • 2I-I20 on the hydration of amorphous calcium aluminate with the chemical composition similar to C,zA7 were studied by determining the degree of hydration according to the selective dissolution method.
The hydration reaction of amorphous calcium aluminate progresses very rapidly and amorphous AH3 is produced along with C2AH8. The reaction is retarded slightly by the addition of Ca(OH)2. When a small amount of Ca504 • 2H20 is added, the degree of hydration is increased compared with the case of no addition. However, the hydration reaction is greatly retarded, in the presence of large amount of CaSO, • 2HH.~O. When Ca(OH)z and CaSO, • 2H20 are added, the retarding effect is larger than in the case of adding 1 mole of CaSO, • 2H20 alone.
📜 SIMILAR VOLUMES
The hydration of C3A in the presence of CaSO4"2H20 , CaCO 3 and always Ca(OH)2 in excess has been studied with X-ray diffraction. Using a special technique the diagrams were taken directly from the pastes. From the data obtained conclusions regarding the sequence of reactions and the possible phase
The reaction between calcium hydroxide and minerals containing alumina forms C~A-hydrates and/or hydrogarnet (calcium-alumina-silicate hydrate), depending on the temperature. Alkali-feldspars furnish alkalies during the reaction. C4A-hydrates react with calcium sulphate to produce ettringite. La
Calculation of the solubility product constants for Ca(OH)2 and CaSO4.2H20 in pore solutions of hardened cement paste is used as an estimation of saturation. The treatment of solubility data using three models is discussed in this paper. These models are the Greenberg-Copeland model[l], the Brornley