In this work, the effect of anodic surface treatment on activated carbons and its Cr(VI) adsorption properties were investigated under reaction-treatment time conditions with 35 wt% HCl solution. The acid-base surface values were determined by Boehm's titration technique. The pore and surface charac
Influence of Anodic Surface Treatment of Activated Carbon on Adsorption and Ion Exchange Properties
β Scribed by Soo-Jin Park; Ki-Dong Kim
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 52 KB
- Volume
- 218
- Category
- Article
- ISSN
- 0021-9797
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β¦ Synopsis
The effect of anodic surface treatment of activated carbon on adsorption and ion exchange characteristics was investigated in the condition of 35 wt% NaOH electrolyte for 60 s. The acid and base values were determined by a titration technique, and surface and pore structures were studied in terms of BET volumetric measurement with N 2 adsorption. The ion exchange capacity of the anodized activated carbons was characterized by a dry weight capacity technique. It was observed that an increase in current intensity leads to an increase in the surface functional groups of activated carbons, resulting in increasing pH, acid-base values, and anion-cation exchange capacities, without significant change of surface and pore structures (i.e., specific surface area, total pore volume, micropore volume, and average pore diameter). Also, anodically treated activated carbons are more effectively evaluated on the base value or cation exchange capacity than on the opposite properties in this electrolytic system.
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3AT, Cardiff (UK) [\*\*] We acknowledge the SLS for the provision of beam time and the EPSRC for a CASTech grant.