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Influence of aluminum Lewis acids on the diastereoselectivity of the nickel-catalyzed [2+2+2] cycloaddition of norbornadiene and electron deficient alkenes

✍ Scribed by Olivier Pardigon; Alphonse Tenaglia; Gérard Buono


Book ID
108379760
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
128 KB
Volume
41
Category
Article
ISSN
0040-4039

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We have recently shown that the aluminum chloride catalyzed reaction of propiolate esters with alkenes yields stereospecific [2+23 cycloadducts and/or ene adducts, depending on the degree of substitution of the double bond?sUnlike other aluminum chloride catalyzed [2+2] cycloaddition reactions of ac