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Influence of alkali metal and ammonium cations on the structure of iron(II) and cobalt(III) hexacyanide complexes encapsulated in faujasite

โœ Scribed by Yu. G. Gol'tsov; L. A. Matkovskaya; V. G. Voloshinets; V. G. Il'in


Book ID
112367911
Publisher
Springer
Year
1995
Tongue
English
Weight
301 KB
Volume
30
Category
Article
ISSN
0040-5760

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The electron transfer step of the reduction of Mn(acac)s and Co(acac)s by Fe(I1) in acetonitrile is preceded by the one-ended dissociation of an acac ligand and the formation of a binuclear bridged complex. After the electron transfer has taken place through the bridging ligand, the complex dissocia