This paper presents the extension of the solid solubility of Mo in Cu by a mechanical alloying technique. Two binary systems, Cu-10 wt.% Mo and Cr-50 wt.% Mo, and one ternary system, Cu-20 wt.% Cr(Mo), are investigated. The solid solubility of Mo in Cu has been shown to be less than 4.3 at.% when th
Influence of Al2O3 nanoparticles on solubility extension of Cr in Cu by mechanical alloying
β Scribed by S. Sheibani; S. Heshmati-Manesh; A. Ataie
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 851 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1359-6454
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β¦ Synopsis
In this study, the effect of the presence of Al 2 O 3 nanoparticles during mechanical alloying on the extension of Cr solid solubility in Cu was investigated. The lattice parameter, dislocation density and crystallite size were evaluated by the X-ray diffraction technique. Also, the microstructure was characterized by scanning electron microscopy and transmission electron microscopy. The final product was a nanocrystalline and supersaturated Cu-Cr solid solution with a mean crystallite size ranging from 8 to 19 nm depending on the composition. The Gibbs free energy changes in these systems due to the dislocation density and crystallite size variations during milling were calculated. It was found that the presence of Al 2 O 3 nanoparticles was beneficial to the process, and this was particularly related to its significant contribution to the increase of strain part of Gibbs free energy changes.
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