The stable nitroxide TEMPO is shown to react with styrene and polystyrene models under conditions typically used for polymerizations. These results show that the nitroxide is not inert at the elevated temperatures necessary to conduct polymerizations. The implications of hydrogen abstraction and ole
✦ LIBER ✦
Influence of Acids on Reaction Rates of Free Radical Scavenging by TEMPO. Relevance to “Living” Free Radical Polymerizations
✍ Scribed by Baldoví, M. V.; Mohtat, N.; Scaiano, J. C.
- Book ID
- 121277752
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 96 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0024-9297
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Reactions of the “stable” nitroxide radi
✍
Terrence J. Connolly; J.C. Scaiano
📂
Article
📅
1997
🏛
Elsevier Science
🌐
French
⚖ 233 KB
Rate Enhancement of Living Free-Radical
✍
Odell, P. G.; Veregin, R. P. N.; Michalak, L. M.; Brousmiche, D.; Georges, M. K.
📂
Article
📅
1995
🏛
American Chemical Society
🌐
English
⚖ 299 KB
Influence of different free radicals on
✍
J. Đorović; J. M. D. Marković; V. Stepanić; N. Begović; D. Amić; Z. Marković
📂
Article
📅
2014
🏛
Springer-Verlag
🌐
English
⚖ 463 KB
Trapping of photogenerated group IV radi
✍
W. G. Skene; Terrence J. Connolly; J. C. Scaiano
📂
Article
📅
2000
🏛
John Wiley and Sons
🌐
English
⚖ 103 KB
👁 1 views
A series of trialkyl and triaryl organometallic radicals from group IV generated by hydrogen abstraction by tert-butoxyl radical from the parent hydrides have been examined using laser flash photolysis. The rate constants for the trapping of the metal-centered radicals by the persistent radical TEMP
Ab Initio Study of Free-Radical Polymeri
✍
V. Van Speybroeck; K. Van Cauter; B. Coussens; M. Waroquier
📂
Article
📅
2005
🏛
John Wiley and Sons
🌐
English
⚖ 384 KB
Mechanism of Rate Enhancement Using Orga
✍
Veregin, Richard P. N.; Odell, Peter G.; Michalak, Lora M.; Georges, Michael K.
📂
Article
📅
1996
🏛
American Chemical Society
🌐
English
⚖ 127 KB