Activity coefficients at infinite dilution γ ∞ i of the linear and branched C 1 to C 6 alcohols, acetone, acetonitrile, ethylacetate, alkylethers, and chloromethanes in the ionic liquid 4-methyl-N -butyl-pyridinium tetrafluoroborate (C 10 H 16 BF 4 N) were determined by gas chromatography using the
Infinite-dilution activity coefficients of organic solutes in methyl phenyl ether, butyl ether and methyl iso-butyl ketone
✍ Scribed by Dr. Enrique A. Campanella
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 255 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0930-7516
No coin nor oath required. For personal study only.
✦ Synopsis
Activity coefficients of hydrocarbons and chloroparaffins at infinite dilution in methyl phenyl ether, butyl ether and methyl iso-butyl ketone at 293.15 K have been obtained by the retentiontime method in a modified gas chromatograph. The experimental data are compared with predictions of the UNIFAC and MOSCED models. Selectivities for the I , I,I-trichloroetane-l,2dichloroetane separation process are reported.
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## Abstract The thermal decomposition reaction of acetone cyclic diperoxide (3,3,6,6‐tetramethyl‐1,2,4,5‐tetroxane, ACDP), in the temperature range of 130.0–166.0°C and initial concentrations range of 0.4–3.1 × 10^−2^ mol kg^−1^ has been studied in methyl __t__‐butyl ether solution. The thermolysis