Tbc mcl~~c ncufron scaumng (INS) spectrum (350-2000 cm-') of potassium hydrogen d~chloromtic~te (sohd staw) hzs been obwlned Two of the nom~I nlodcs oivlbrauon of tic hydrogen bond [y(OHO) md 6 (OHO)] WCIC obsemcd and a.wgncd No INS band v&OHO) was obscrvcd rn the rcpon 500-1300 cm-'. THIS confbc~~
Inelastic neutron scattering of molecular hydrogen in amorphous hydrogenated carbon
โ Scribed by P.J.R. Honeybone; R.J. Newport; W.S. Howells; J. Tomkinson; S.B. Bennington; P.J. Revell
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 278 KB
- Volume
- 180
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
We have, by use of inelastic neutron scattering, detected the presence of molecular hydrogen in amorphous hydrogenated carbon, We have found the hydrogen to be in a high-pressure, asymmetric environment formed by the compressive stresses in the a-C : H films. On comparing two samples, we have also found that the sample with higher molecular hydrogen concentration has a lower total hydrogen composition. This is caused by a higher network density, trapping the molecular hydrogen during network growth.
๐ SIMILAR VOLUMES
The behavior of chemisorbed hydrogen in potassium intercalated graphite has been probed by inelastic neutron scattering at a mean momentum transfer, Q, of 39 A-' using a resonance detector neutron spectrometer. At these high Q's the scattering is approximately described by the impulse approximation
Inehstic neutron scattering spectra of KHCO3 and CsH(NO& have been obtained in the region 400 -. 2400 and 400 -+ 2800 cm-' respectively\_ The in-and out-ofqhase bending vibrations of the hydrogen bonds have been observed and assigned. For CsH(NO& the two bending modes are closer in frequency than in